Adsorption of rare earth elements (Ce 3+, La 3+, and Nd 3+) and recovery from phosphogypsum leachate using a novel ZSM-5 zeolite

Abstract

ZSM-5 zeolite is a multifunctional material highly efficient for adsorbing ions. Our ZSM-5 was synthesized by employing a nucleating gel as a structure -directing agent, followed by homogenization and hydrothermal treatment. The as -prepared ZSM-5 was physicochemically characterized to assess its properties. Next, the asprepared zeolite was employed as an adsorbent to remove rare earth elements, REEs from synthetic solutions and real phosphogypsum leachate under batch mode operation. As expected, the ZSM-5 adsorbent was discovered to be highly microporous with abundant surface functionalities, which could positively impact REE adsorption. The adsorption data indicated a high affinity between ZSM-5 and all three REEs with rapid kinetics and high adsorption capacities. The modeling study suggested that the adsorption kinetic data were well fitted by Avrami-fractional order, and Liu described the equilibrium data. The maximum adsorption capacity for Ce 3+ , La 3+ , and Nd 3+ were 99.42 mg g -1 , 96.43 mg g -1 , 118.10 mg g -1 , respectively. Further, the thermodynamic analysis revealed that the interaction between ZSM-5 and Ce 3+ , La 3+ , and Nd 3+ was favorable, spontaneous, and endothermic. The efficiency of ZSM-5 adsorbent was also studied in recovering several REEs from leachate of phosphogypsum wastes, and the data results proved its potency to do so. The findings reported in this work support the idea that ZSM-5 can be successfully used as an adsorbent to recover REEs from synthetic and real samples.

Keywords

Microporous zeolite; Adsorption of rare earth elements; Ion -exchange mechanism

Published in

Colloids and Surfaces A: Physicochemical and Engineering Aspects
2024, volume: 698, article number: 134549

SLU Authors

• Simões Dos Reis, Glaydson

  • Department of Forest Biomaterials and Technology, Swedish University of Agricultural Sciences
    

UKÄ Subject classification

Materials Chemistry

Publication identifier

• DOI: https://doi.org/10.1016/j.colsurfa.2024.134549

Permanent link to this page (URI)

https://res.slu.se/id/publ/130974