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Abstract

Polymerization isomerism is potentially important for metal alkoxides as precursors of oxide materials. Here, we present this phenomenon for tungsten oxo-methoxide, reporting the molecular and crystal structure of its polymeric form [WO(OMe)4]infinity(1), its dimeric form W2O2(OMe)8(2), and a higher extent oxo-substituted by-product of the synthesis, Li2(MeOH)6W12O29(OMe)16(3).

Published in

Dalton Transactions
2025, volume: 54, number: 19
Publisher: ROYAL SOC CHEMISTRY

SLU Authors

UKÄ Subject classification

Inorganic Chemistry

Publication identifier

  • DOI: https://doi.org/10.1039/d5dt00348b

Permanent link to this page (URI)

https://res.slu.se/id/publ/142552