Asymmetric hydrogenation of enol phosphinates by iridium catalysts having N,P ligands

Abstract

Enol phosphinates, which are structural analogues of enol acetates, have for the first time been employed as substrates for Ir-catalyzed asymmetric hydrogenation. A number of enol phosphinates have been synthesized and reduced successfully with up to and above 99% ee.

Published in

Organic Letters
2007, volume: 9, number: 9, pages: 1659-1661
Publisher: AMER CHEMICAL SOC

SLU Authors

• Gohil, Suresh

  • Department of Molecular Sciences, Swedish University of Agricultural Sciences
    

Publication identifier

• DOI: https://doi.org/10.1021/ol070325l

Permanent link to this page (URI)

https://res.slu.se/id/publ/15682