Skip to main content
SLU publication database (SLUpub)

Abstract

Minor compounds such as tocopherols and phytosterols in vegetable oils play an important role in their stability and nutritional value. This study monitored the effects of chemical interesterification on the levels of tocopherols, tocotrienols, phytosterols and phytosterol oxidation products (POPs) in an olive oil and palm stearin blend (50/50 w/w). Tocopherols and tocotrienols were dominated by alpha-tocopherol (192 ppm) and gamma-tocotrienol (70 ppm) and decreased during interesterification. Among the tocopherols, delta-tocotrienol had the highest decrease (35%) at 120 degrees C. During interesterification at 90 and 120 degrees C, total sterol content in the oil blend (509 ppm) declined slightly, by 3 and 5%, respectively. Phytosterols were esterified at a higher level at 120 degrees C (7%) than at 90 degrees C (4%) during this process. Distribution of fatty acids in the esterified sterols followed the fatty acid composition of the oil blend. Total POP content was 4.3 ppm, and remained generally unchanged during interesterification. Among the nine POPs tentatively identified by their mass spectra, 6-hydroxysitostanol and 6-hydroxycampestanol dominated in the oil blend and in the interesterified product. The formation pathways of these saturated di-hydroxyphytosterols have yet to be identified. Although the interesterification process comprised several treatments, there were only minor losses of tocopherols and phytosterols and virtually no increases in the POPs.

Keywords

interesterification; minor lipid components; olive oil; palm stearin; phytosterols; phytosterol oxidation products; POPs; sterol esters; tocopherols; tocotrienols

Published in

Journal of the American Oil Chemists' Society
2008, volume: 85, number: 1, pages: 13-21
Publisher: SPRINGER

SLU Authors

UKÄ Subject classification

Food Science

Publication identifier

  • DOI: https://doi.org/10.1007/s11746-007-1170-1

Permanent link to this page (URI)

https://res.slu.se/id/publ/20770