Molecular structure design and synthetic approaches to the heterometallic alkoxide complexes (soft chemistry approach to inorganic materials by the eyes of a crystallographer)

Kessler, VG

doi:10.1039/b209168m

Abstract

General principles of formation and stability of the heterometallic alkoxides existing due to Lewis Acid-Base interaction, isomorphous substitution and heterometallic metal-metal bonds are discussed. The molecular structure design approach based on the choice of a proper molecular structure type and completing it with the ligands, providing both the necessary number of donor atoms and the sterical protection of the metal oxygen core, is presented. Its applications in prediction of the composition and structure of single source precursors of inorganic materials are demonstrated for such classes of compounds as oxoalkoxides, alkoxide beta-diketonates, alkoxide carboxylates, derivatives of functional alcohols, metallatranes and metallasiloxanes.

Published in

Chemical Communications
2003, number: 11, pages: 1213-1222
Publisher: ROYAL SOC CHEMISTRY

SLU Authors

Kessler, Vadim
- Department of Molecular Sciences, Swedish University of Agricultural Sciences

UKÄ Subject classification

Inorganic Chemistry

Publication identifier

DOI: https://doi.org/10.1039/b209168m

Permanent link to this page (URI)

https://res.slu.se/id/publ/577