A family of [Ni-8] cages templated by mu(6)-peroxide from dioxygen activation

Abstract

A family of exceptionally thermally stable [Ni-8] cages is reported, each being templated by a rare eta(3):eta(3):mu(6)-O-2(2-) species produced by dioxygen activation, where the reducing agent for the O-2 reduction appears to be the ligand used in the reaction mixtures, which was found within the nickel cages in its oxidized form.

Published in

Inorganic Chemistry Frontiers
2014, volume: 1, number: 6, pages: 487-494
Publisher: CHINESE CHEMICAL SOC

SLU Authors

• Kessler, Vadim

  • Department of Molecular Sciences, Swedish University of Agricultural Sciences
    

UKÄ Subject classification

Biochemistry
Inorganic Chemistry
Molecular Biology

Publication identifier

• DOI: https://doi.org/10.1039/c4qi00048j

Permanent link to this page (URI)

https://res.slu.se/id/publ/77155