Unexpected structural analogy between early and late 3d transition metal alkoxide carboxylates: Synthesis and single crystal X-ray study of Ni-6(OH)(2)(ORN)(6)(OCOR)(2), R-N= C2H4NMe2, R = H, CH3

Ilina E, Kessler VG

doi:10.1016/j.poly.2005.06.054

Abstract

Modification of the liquid Ni(ORN)(2) R-N = C2H4NMe2, with stoichiometric or sub-stoichiometric amounts of carboxylic acids, HCOOH or CH3COOH, results in formation of crystalline heteroleptic complexes Ni-6(OH)(2)(ORN)(6)(OCOR)(2) R = H (1) CH3 (3) with the core structure closely analogous to that observed earlier for hexanuclear titanium (IV) alkoxide carboxylates and derived from hexagonal packing of the donor atoms. (c) 2005 Elsevier Ltd. All rights reserved

Keywords

Nickel alkoxides; Molecular precursors; Chemical modi.cation; Acidic reagents; Hybrid magnetic materials

Published in

Polyhedron
2005, volume: 24, number: 18, pages: 3052-3056
Publisher: PERGAMON-ELSEVIER SCIENCE LTD

SLU Authors

Kessler, Vadim
- Department of Molecular Sciences, Swedish University of Agricultural Sciences

UKÄ Subject classification

Inorganic Chemistry

Publication identifier

DOI: https://doi.org/10.1016/j.poly.2005.06.054

Permanent link to this page (URI)

https://res.slu.se/id/publ/8009