Skip to main content
SLU publication database (SLUpub)

Abstract

Herein, we report on the use a biohybrid catalyst consisting of palladium nanoparticles immobilized on cross-linked enzyme aggregates of lipase B of Candida antarctica (CalB CLEA) for the dynamic kinetic resolution (DKR) of benzylic amines. A set of amines were demonstrated to undergo an efficient DKR and the recyclability of the catalysts was studied. Extensive efforts to further elucidate the structure of the catalyst are presented.

Keywords

amides; biohybrid catalysts; dynamic kinetic resolution; heterogeneous catalysis; key cross-linked enzyme aggregates

Published in

Chemistry - A European Journal
2019, volume: 25, number: 39, pages: 9174-9179
Publisher: WILEY-V C H VERLAG GMBH

SLU Authors

UKÄ Subject classification

Organic Chemistry

Publication identifier

  • DOI: https://doi.org/10.1002/chem.201901418

Permanent link to this page (URI)

https://res.slu.se/id/publ/101218