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Abstract

Soil dissolved organic matter (DOM) plays an essential role in the Three Gorges Reservoir (TGR) as a linkage between terrestrial and aquatic systems. In particular, the reducing capacities of soil DOM influence the geochemistry of contaminants such as mercury (Hg). However, few studies have investigated the molecular information of soil DOM and its relationship with relevant geochemical reactivities, including redox properties. We collected samples from eight sites in the TGR areas and studied the link between the molecular characteristics of DOM and their electron donation capacities (EDCs) toward Hg(II). The average kinetic rate and EDC of soil DOM in TGR areas were (0.004 +/- 0.001) hr(-1) and (2.88 +/- 1.39) nmol e(-)/mg DOMbulk, respectively. Results suggest that higher EDCs and relatively rapid kinetics were related to the greater electron donating components of lignin-derived and perhaps pyrogenic DOM, which are the aromatic constituents that influenced the reducing capacities of DOM in the present study. Molecular details revealed that even the typical autochthonous markers are important for the EDCs of DOM as well, in contrast to what is generally assumed. More studies identifying specific DOM molecular components involved in the abiotic reduction of Hg(II) are required to further understand the relations between DOM sources and their redox roles in the environmental fate of contaminants. (C) 2019 The Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences. Published by Elsevier B.V.

Keywords

Soil dissolved organic matter; Reducing capacity; Three Gorges Reservoir; Pyrolysis; Natural organic matter; Mercury

Published in

Journal of Environmental Sciences
2020, volume: 90, pages: 146-156
Publisher: SCIENCE PRESS

SLU Authors

UKÄ Subject classification

Environmental Sciences

Publication identifier

  • DOI: https://doi.org/10.1016/j.jes.2019.11.007

Permanent link to this page (URI)

https://res.slu.se/id/publ/104819