Kessler, Vadim
- Department of Molecular Sciences, Swedish University of Agricultural Sciences
Research article2021Peer reviewedOpen access
Samii, Rouzbeh; Zanders, David; Fransson, Anton; Bacic, Goran; Barry, Sean T.; Ojamae, Lars; Kessler, Vadim; Pedersen, Henrik; O'Brien, Nathan J.
Only a few M-N bonded divalent group 14 precursors are available for vapor deposition, in particular for Ge and Pb. A majority of the reported precursors are dicoordinated with the Sn(II) amidinates, the only tetracoordinated examples. No Ge(II) and Pb(II) amidinates suitable for vapor deposition have been demonstrated. Herein, we present tetracoordinated Ge(II), Sn(II), and Pb(II) complexes bearing two sets of chelating 1,3-di-tert-butyltriazenide ligands. These compounds are thermally stable, sublime quantitatively between 60 and 75 degrees C (at 0.5 mbar), and show ideal single-step volatilization by thermogravimetric analysis.
Inorganic Chemistry
2021, Volume: 60, number: 17, pages: 12759-12765
Publisher: AMER CHEMICAL SOC
Materials Chemistry
DOI: https://doi.org/10.1021/acs.inorgchem.1c00695
https://res.slu.se/id/publ/113766