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Research article - Peer-reviewed, 2022

Facile Synthesis of Sustainable Biomass-Derived Porous Biochars as Promising Electrode Materials for High-Performance Supercapacitor Applications

Lima, Ravi Moreno Araujo Pinheiro; dos Reis, Glaydson Simoes; Thyrel, Mikael; Alcaraz-Espinoza, Jose Jarib; Larsson, Sylvia H.; de Oliveira, Helinando Pequeno

Abstract

Preparing sustainable and highly efficient biochars as electrodes remains a challenge for building green energy storage devices. In this study, efficient carbon electrodes for supercapacitors were prepared via a facile and sustainable single-step pyrolysis method using spruce bark as a biomass precursor. Herein, biochars activated by KOH and ZnCl2 are explored as templates to be applied to prepare electrodes for supercapacitors. The physical and chemical properties of biochars for application as supercapacitors electrodes were strongly affected by factors such as the nature of the activators and the meso/microporosity, which is a critical condition that affects the internal resistance and diffusive conditions for the charge accumulation process in a real supercapacitor. Results confirmed a lower internal resistance and higher phase angle for devices prepared with ZnCl2 in association with a higher mesoporosity degree and distribution of Zn residues into the matrix. The ZnCl2-activated biochar electrodes' areal capacitance reached values of 342 mF cm(-2) due to the interaction of electrical double-layer capacitance/pseudocapacitance mechanisms in a matrix that favors hydrophilic interactions and the permeation of electrolytes into the pores. The results obtained in this work strongly suggest that the spruce bark can be considered a high-efficiency precursor for biobased electrode preparation to be employed in SCs.

Keywords

spruce bark electrodes; spruce bark-supercapacitors; impedance; areal capacitance; electrical double layer capacitance

Published in

Nanomaterials
2022, volume: 12, number: 5, article number: 866
Publisher: MDPI

Authors' information

Lima, Ravi Moreno Araujo Pinheiro
Universidade Federal do Vale do Sao Francisco
Swedish University of Agricultural Sciences, Department of Forest Biomaterials and Technology
Alcaraz-Espinoza, Jose Jarib
Universidad Autonoma Metropolitana - Mexico
Swedish University of Agricultural Sciences, Department of Forest Biomaterials and Technology
de Oliveira, Helinando Pequeno
Universidade Federal do Vale do Sao Francisco

Sustainable Development Goals

SDG7 Affordable and clean energy

UKÄ Subject classification

Bio Materials
Materials Chemistry

Publication Identifiers

DOI: https://doi.org/10.3390/nano12050866

URI (permanent link to this page)

https://res.slu.se/id/publ/116594