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Research article - Peer-reviewed, 2008

Degradation of polyethylene glycol and hemicellulose in the Vasa

Almkvist, Gunnar; Persson, Ingmar

Abstract

Mass spectrometric analysis of aqueous wood extracts from the Swedish warship Vasa reveals a serious chemical condition in the depth of the wood. The surface is less affected. Polyethylene glycol, used as conservation agent, is affected and partly degraded, and low-molecular fragments from hemicellulose are found at sites with high iron content and low pH. These findings imply a catalytic oxidative process and acidic hydrolysis in the wood, which contributes to a new picture of the challenge of long-term preservation of the Vasa.

Keywords

catalytic oxidation; hemicelluloses; hydrolysis; matrix-assisted laser desorption/ionization-time of flight (MALDI-TOF); polyethylene glycol; Vasa; wood degradation

Published in

Holzforschung
2008, volume: 62, number: 1, pages: 64-70
Publisher: WALTER DE GRUYTER & CO

Authors' information

Almkvist, Gunnar
Swedish University of Agricultural Sciences, Department of Chemistry
Swedish University of Agricultural Sciences, Department of Chemistry

UKÄ Subject classification

Forest Science

Publication Identifiers

DOI: https://doi.org/10.1515/HF.2008.009

URI (permanent link to this page)

https://res.slu.se/id/publ/15612