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Research article - Peer-reviewed, 2004

Nanomaterials based on Re-Mo oxomethoxide binuclear complexes and zeolites: Acidity and catalytic activity

Kustov AL, Kessler VG, Romanovskii BV, Seisenbaeva GA, Drobot DV, Shcheglov PA

Abstract

The acidic properties of mono- and bimetal Re and Mo oxide clusters immobilized in microporous NaY zeolite were studied using the temperature-programmed desorption technique. It was established that the strength of acidic sites at the clusters decreases in the series ReMoO6 > ReO3 > MoO3. It was found that the acidic properties of the clusters correlate with their catalytic activity in the conversion of methanol

Published in

Russian Journal of Physical Chemistry A, Focus on Chemistry / Zhurnal fizicheskoi khimii
2004, Volume: 78, pages: S68-S71
Publisher: INTERPERIODICA