Persson, Ingmar
- The Department of Chemistry and Biotechnology, Swedish University of Agricultural Sciences
Research article2013Peer reviewed
Crystal structure of [Eu(CyMe4-BTBP)(2)kappa O-2,O '-(NO3)](NO3)(2)center dot n-C8H17OH and its structure in 1-octanol solution
Ekberg, Christian; Persson, Ingmar; Lundberg, Daniel
Abstract
The structure of the [Eu(CyMe4-BTBP)(2)(NO3)(n)]((3-n)+) complex in 1-octanol solution and solid state has been determined by EXAFS and X-ray crystallography. The crystal structure shows that 1-octanol binds only to the europium(III)-coordinated BTBP molecules through weak van der Waals forces, making it the first indication of the role of the extraction solvent.
Published in
Dalton Transactions
2013, volume: 42, number: 11, pages: 3767-3770
Publisher: ROYAL SOC CHEMISTRY
SLU Authors
Lundberg, Daniel
- The Department of Chemistry and Biotechnology, Swedish University of Agricultural Sciences
- The Department of Chemistry and Biotechnology, Swedish University of Agricultural Sciences
UKÄ Subject classification
Inorganic Chemistry
Publication identifier
- DOI: https://doi.org/10.1039/c2dt32317f
Permanent link to this page (URI)
https://res.slu.se/id/publ/41287