Binuclear Pt-TI Bonded Complex with Square Pyramidal Coordination around Pt: A Combined Multinuclear NMR, EXAFS, UV-Vis, and DFT/TDDFT Study in Dimethylsulfoxide Solution

Purgel, Mihály; Maliarik, Mikhail; Glaser, Julius; Platas-Iglesias, Carlos; Persson, Ingmar; Tóth, Imre

doi:10.1021/ic200417q

Research article2011Peer reviewed

Binuclear Pt-TI Bonded Complex with Square Pyramidal Coordination around Pt: A Combined Multinuclear NMR, EXAFS, UV-Vis, and DFT/TDDFT Study in Dimethylsulfoxide Solution

Purgel, Mihály; Maliarik, Mikhail; Glaser, Julius; Platas-Iglesias, Carlos; Persson, Ingmar; Tóth, Imre

Abstract

This bonding scheme may rationalize the smaller thermodynamic stability of this adduct compared to the related complexes with (CN)(5)Pt-Tl entity, wher the linear C-Pt-Tl unit constitutes a very stable bonding system.

Published in

Inorganic Chemistry
2011, Volume: 50, number: 13, pages: 6163-6173 Publisher: AMER CHEMICAL SOC

SLU Authors

Persson, Ingmar
- Department of Molecular Sciences, Swedish University of Agricultural Sciences

UKÄ Subject classification

Inorganic Chemistry

Publication identifier

DOI: https://doi.org/10.1021/ic200417q

Permanent link to this page (URI)

https://res.slu.se/id/publ/46530