Seisenbaeva, Gulaim
- Department of Molecular Sciences, Swedish University of Agricultural Sciences
The molecular structures of the species crystallizing from solutions of alkoxytitanasilsesquioxanes in hydrocarbons upon reflux confirm the partial release of solvating alcohol. They feature, however, distinctly the formation of a dinuclear core with preserved hexacoordination for the metal atoms. The active titanium centers in the silica-titania epoxidation catalysts, lacking the sterically demanding ligands, are thus quite probably also hexacoordinated.
Inorganic Chemistry
2009, volume: 48, number: 19, pages: 9063-9065
Publisher: AMER CHEMICAL SOC
Environmental Sciences and Nature Conservation
Fish and Aquacultural Science
https://res.slu.se/id/publ/49342