The effect of a magnetic field on a RAPET (reaction under autogenic pressure at elevated temperature) of MoO(OMe)(4): Fabrication of MoO2 nanoparticles coated with carbon or separated MoO2 and carbon particles

Pol, S. V.; Pol, V. G.; Kessler, Vadim; Seisenbaeva, Gulaim; Sung, M.; Asai, S.; Gedanken, A.

doi:10.1021/jp0491360

Research article2004Peer reviewed

The effect of a magnetic field on a RAPET (reaction under autogenic pressure at elevated temperature) of MoO(OMe)(4): Fabrication of MoO2 nanoparticles coated with carbon or separated MoO2 and carbon particles

Pol, S. V.; Pol, V. G.; Kessler, Vadim; Seisenbaeva, Gulaim; Sung, M.; Asai, S.; Gedanken, A.

Abstract

In this article, we present results of the RAPET dissociation of MoO(OMe)(4) at 700 degreesC in a closed Swagelok cell. The reaction produces molybdenum dioxide nanoparticles (20 nm) coated with carbon (20 nm). We have also carried out the same reaction under an applied magnetic field of 10 T. This reaction yielded different products. It produces a mixture of comparatively larger (50 nm) molybdenum dioxide nanoparticles and separated uncoated carbon particles (20-30 nm).

Published in

Journal of Physical Chemistry B
2004, Volume: 108, number: 20, pages: 6322-6327
Publisher: AMER CHEMICAL SOC

SLU Authors

Kessler, Vadim
- Department of Molecular Sciences, Swedish University of Agricultural Sciences

Seisenbaeva, Gulaim
- Department of Molecular Sciences, Swedish University of Agricultural Sciences

UKÄ Subject classification

Inorganic Chemistry
Nano-technology
Materials Chemistry

Publication identifier

DOI: https://doi.org/10.1021/jp0491360

Permanent link to this page (URI)

https://res.slu.se/id/publ/50542