Abstract

Significant resources are spent on counteracting the effects of acidification, mainly by liming. Due to lower S and N deposition in Europe and North America, authorities are changing directives and strategies for remediation and reducing liming. However, as the acid-base buffer capacity differs in different water bodies, the desirable reduction of the lime dose is variable. In this study, a geochemical model is used to predict pH and inorganic monomeric Al (Ali) when liming is reduced and finally terminated in the 3000 Swedish lakes currently treated with lime. To estimate Ca and Mg concentrations not affected by liming for use in the model, the Ca/Mg ratio in nearby unlimed reference lakes was used. For the modelling of pH and inorganic Al the Visual MINTEQ program including the Stockholm Humic Model recently calibrated for Swedish fresh water was used. The predictions were validated with modelling results from six monitored lakes, in which liming had been terminated. The use of geochemical modelling appeared to be a promising tool for the calculation of accurate lime requirements in acid waters. For simulations in which liming was completely terminated, the pH value decreased by, on average, 1 pH unit to pH 5.7, whereas Ali increased by 17 mu g L (1) to 32 mu g L (1). If liming was reduced by half, the pH would drop only 0.3 pH units and Ali would increase by 2 mu g L (1). Lakes in the south-western part of Sweden were predicted to reach a lower pH and higher Ali, which would be expected due to their greater historical S deposition. The results indicate that liming can be terminated in certain areas and in other areas be reduced without increases in the lake acidity. (C) 2013 Elsevier Ltd. All rights reserved.

Published in

Applied Geochemistry
2013, Volume: 35, pages: 221-229
Publisher: PERGAMON-ELSEVIER SCIENCE LTD

SLU Authors

• Fölster, Jens

  • Department of Aquatic Sciences and Assessment, Swedish University of Agricultural Sciences
    

• Gustafsson, Jon-Petter

  • Department of Soil and Environment, Swedish University of Agricultural Sciences
    

UKÄ Subject classification

Geochemistry
Environmental Sciences


Publication identifier

DOI: https://doi.org/10.1016/j.apgeochem.2013.04.014

Permanent link to this page (URI)

https://res.slu.se/id/publ/51209