Kessler, Vadim
- Department of Molecular Sciences, Swedish University of Agricultural Sciences
Research article - Peer-reviewed, 2003
Characterization of small azocrown ether stereoisomers
Luboch E, Wagner-Wysiecka E, Kravtsov VC, Kessler V
Abstract
The stable E- and Z-isomers of 10-membered azocrown ether have been isolated and studied by X-ray, (HNMR)-H-1 and UV-Vis methods. Their structures in a solid state indicate. the stretched conformation for trans-isomer and unstressed for cis-isomer. The concerted effect of azo-group pi-conjugation with benzene residue and steric strain of molecular conformation results in the observed stability of isomers
Published in
Polish Journal of Chemistry
2003, Volume: 77, number: 2, pages: 189-196
Publisher: POLISH CHEMICAL SOCIETY
SLU Authors
Permanent link to this page (URI)
https://res.slu.se/id/publ/572