XANES Speciation of P in Environmental Samples: An Assessment of Filter Media for on-Site Wastewater Treatment

Abstract

X-ray absorption near edge structure VANES) spectroscopy is a useful technique for characterization of chemical species of phosphorus in complex environmental samples. To develop and evaluate bed filters as sustainable on-site wastewater treatment solutions, our objective in this study was to determine the chemical forms of accumulated phosphorus in a selection of promising filter materials: Filtralite P, Filtra P, Polonite, Absol, blast furnace slag, and wollastonite. Full-scale operational wastewater-treatment systems were sampled and in addition, filter samples collected from laboratory studies provided access to additional media and complementary samples. Phosphorus species were characterized using phosphorus K-edge XANES spectroscopy, complemented by X-ray powder diffraction (XRPD) and attenuated total reflectance Fourier-transform infrared spectroscopy (ATR-FTIR). No systematic differences could be seen in the results between laboratory and full-scale samples. All six filter media contained significant amounts of crystalline calcium phosphates. Some samples also contained amorphous calcium phosphate (>60% of total P in Absol). In Filtralite P and blast furnace slag, more than 35% of the accumulated phosphorus was associated with Fe or Al. Both the power and shortcomings of XANES analysis for characterizing P species in these filter media are discussed.

Published in

Environmental Science and Technology
2009, volume: 43, number: 17, pages: 6515-6521
Publisher: AMER CHEMICAL SOC

SLU Authors

• Gustafsson, Jon-Petter

  • Royal Institute of Technology (KTH)

• Hillier, Stephen

  • The Macaulay Land Use Research Institute

UKÄ Subject classification

Environmental Management
Geochemistry

Publication identifier

• DOI: https://doi.org/10.1021/es901084z

Permanent link to this page (URI)

https://res.slu.se/id/publ/69484