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Research article - Peer-reviewed, 2014

A family of [Ni-8] cages templated by mu(6)-peroxide from dioxygen activation

Perviolaris, Alexandros; Stoumpos, Constantinos; Karpinska, Jolanta; Ryder, Alan; Frost, Jamie; Mason, Kevin; Prescimone, Alessandro; Slawin, Alexandra; Kessler, Vadim; Mathieson, Jennifer; Cronin, Leroy; Brechin, Euan; Papaefstathiou, Giannis S.

Abstract

A family of exceptionally thermally stable [Ni-8] cages is reported, each being templated by a rare eta(3):eta(3):mu(6)-O-2(2-) species produced by dioxygen activation, where the reducing agent for the O-2 reduction appears to be the ligand used in the reaction mixtures, which was found within the nickel cages in its oxidized form.

Published in

Inorganic Chemistry Frontiers
2014, volume: 1, number: 6, pages: 487-494
Publisher: CHINESE CHEMICAL SOC

Authors' information

Perviolaris, Alexandros
National and Kapodistrian University of Athens
Stoumpos, Constantinos
National and Kapodistrian University of Athens
Karpinska, Jolanta
National University of Ireland Galway (NUI Galway)
Ryder, Alan
National University of Ireland Galway (NUI Galway)
Frost, Jamie
University of Edinburgh
Mason, Kevin
University of Edinburgh
Prescimone, Alessandro
University of Edinburgh
Slawin, Alexandra
University of St Andrews
Swedish University of Agricultural Sciences, Department of Chemistry
Mathieson, Jennifer
University of Glasgow
Cronin, Leroy
University of Glasgow
Brechin, Euan
University of Edinburgh
Papaefstathiou, Giannis S.
National and Kapodistrian University of Athens

UKÄ Subject classification

Inorganic Chemistry
Biochemistry and Molecular Biology

Publication Identifiers

DOI: https://doi.org/10.1039/c4qi00048j

URI (permanent link to this page)

https://res.slu.se/id/publ/77155