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Research article - Peer-reviewed, 2014

A family of [Ni-8] cages templated by mu(6)-peroxide from dioxygen activation

Perviolaris, Alexandros; Stoumpos, Constantinos; Karpinska, Jolanta; Ryder, Alan; Frost, Jamie; Mason, Kevin; Prescimone, Alessandro; Slawin, Alexandra; Kessler, Vadim; Mathieson, Jennifer; Cronin, Leroy; Brechin, Euan; Papaefstathiou, Giannis S.

Abstract

A family of exceptionally thermally stable [Ni-8] cages is reported, each being templated by a rare eta(3):eta(3):mu(6)-O-2(2-) species produced by dioxygen activation, where the reducing agent for the O-2 reduction appears to be the ligand used in the reaction mixtures, which was found within the nickel cages in its oxidized form.

Published in

Inorganic Chemistry Frontiers
2014, Volume: 1, number: 6, pages: 487-494
Publisher: CHINESE CHEMICAL SOC

    UKÄ Subject classification

    Inorganic Chemistry
    Biochemistry and Molecular Biology

    Publication identifier

    DOI: https://doi.org/10.1039/c4qi00048j

    Permanent link to this page (URI)

    https://res.slu.se/id/publ/77155