The synthesis of iron (III) ethoxide revisited: Characterization of the metathesis products of iron (III) halides and sodium ethoxide

Seisenbaeva GA, Gohil S, Suslova EV, Rogova TV, Turova NY, Kessler VG

doi:10.1016/j.ica.2005.03.048

Research article - Peer-reviewed, 2005

The synthesis of iron (III) ethoxide revisited: Characterization of the metathesis products of iron (III) halides and sodium ethoxide

Seisenbaeva GA, Gohil S, Suslova EV, Rogova TV, Turova NY, Kessler VG

Abstract

interaction of FeX3, X = Cl, Br with 3 equiv. of NaOEt in toluene/ethanol media provides mixtures of iron (III) oxoethoxide, Fe5O(OEt)(13), and its halide alkoxide analogs. The latter have been identified by mass-spectrometric study as Fe5O(OEt)(12)X and Fe5O(OEt)(11)X-2. Application of FeBr3 as a starting material leads to much more pure samples of Fe5O(OEt)(13) isolated with higher yields. (c) 2005 Elsevier B.V. All rights reserved

Keywords

Iron oxo-ethoxide; Mass-spectrometry; X-ray study; Sol–gel

Published in

Inorganica Chimica Acta
2005, volume: 358, number: 12, pages: 3506-3512
Publisher: ELSEVIER SCIENCE SA

Authors' information

Seisenbaeva, Gulaim

Swedish University of Agricultural Sciences, Department of Chemistry

Gohil, Suresh

Swedish University of Agricultural Sciences, Department of Chemistry

Kessler, Vadim

Swedish University of Agricultural Sciences, Department of Chemistry

Rogova, Tatiana V.

Suslova, Evgeniya V.

Turova, Nataliya Ya.

Publication Identifiers

DOI: https://doi.org/10.1016/j.ica.2005.03.048

URI (permanent link to this page)

https://res.slu.se/id/publ/7993