Research article - Peer-reviewed, 2005
The synthesis of iron (III) ethoxide revisited: Characterization of the metathesis products of iron (III) halides and sodium ethoxide
Seisenbaeva GA, Gohil S, Suslova EV, Rogova TV, Turova NY, Kessler VGAbstract
interaction of FeX3, X = Cl, Br with 3 equiv. of NaOEt in toluene/ethanol media provides mixtures of iron (III) oxoethoxide, Fe5O(OEt)(13), and its halide alkoxide analogs. The latter have been identified by mass-spectrometric study as Fe5O(OEt)(12)X and Fe5O(OEt)(11)X-2. Application of FeBr3 as a starting material leads to much more pure samples of Fe5O(OEt)(13) isolated with higher yields. (c) 2005 Elsevier B.V. All rights reservedKeywords
Iron oxo-ethoxide; Mass-spectrometry; X-ray study; Sol–gelPublished in
Inorganica Chimica Acta2005, volume: 358, number: 12, pages: 3506-3512
Publisher: ELSEVIER SCIENCE SA
Authors' information
Swedish University of Agricultural Sciences, Department of Chemistry
Swedish University of Agricultural Sciences, Department of Chemistry
Swedish University of Agricultural Sciences, Department of Chemistry
Rogova, Tatiana V.
Suslova, Evgeniya V.
Turova, Nataliya Ya.
Publication Identifiers
DOI: https://doi.org/10.1016/j.ica.2005.03.048
URI (permanent link to this page)
https://res.slu.se/id/publ/7993