Abstract

Membrane hybrid processes-coagulation coupled with ultrafiltration (UF)-have become a common method to comply with the legal, chemical, and microbiological requirements for drinking water. The main advantages of integrating coagulation with membrane filtration are the enhanced removal of natural organic matter (NOM) and reduced membrane fouling. With in-line coagulation, coagulants are patched into the feed stream directly prior to the membrane process, without removing the coagulated solids. Compared with conventional coagulation/sedimentation, in-line coagulation/membrane reduces the treatment time and footprint. Coagulant dosing could be challenging in raw water of varying quality; however, with relatively stable specific ultraviolet absorbance (SUVA), dosing can be controlled. Recent studies indicate that UV absorbance correlates well with humic substances (HS), the major fraction to be removed during coagulation. This paper describes and evaluates a 30-month UF pilot trial on the surface water of Lake Neden (Sweden), providing drinking water to 60,000 residents. In this study, automatic coagulant dosing based on online measurement was successfully applied. Online sensor data were used to identify the current optimal aluminium coagulation conditions (0.5-0.7 mg L-1) and the potential boundaries (0.9-1.2 mg L-1) for efficient future (2040) NOM removal. The potential increase in NOM could affect the Al dose and drinking water quality significantly within 20 years, should the current trends in dissolved organic carbon (DOC) prevail. UV absorbance, the freshness index, and liquid chromatography-organic carbon detection (LC-OCD) measurements were used to optimise the process. Careful cross-calibration of raw and filtered samples is recommended when using online sensor data for process optimisation, even in low-turbidity water (formazin nephelometric unit (FNU) < 5).

Keywords

ultrafiltration; hollow fibre; natural organic matter (NOM); coagulation; optical sensors

Published in

Water
2017, Volume: 9, number: 9, article number: 697

SLU Authors

• Köhler, Stephan

  • Department of Aquatic Sciences and Assessment, Swedish University of Agricultural Sciences
    

Sustainable Development Goals

Ensure availability and sustainable management of water and sanitation for all


UKÄ Subject classification

Chemical Process Engineering
Analytical Chemistry


Publication identifier

DOI: https://doi.org/10.3390/w9090697

Permanent link to this page (URI)

https://res.slu.se/id/publ/89836