Abstract

X-ray absorption spectroscopy (XAS) includes well-established methods to study the local structure around the absorbing element – extended X-ray absorption fine structure (EXAFS), and the effective oxidation number or to quantitatively determine the speciation of an element in a complex matrix – X-ray absorption near-edge structure (XANES). The increased brilliance and intensities available at the new generation of synchrotron light sources makes it possible to study, in-situ and in-operando, much more dilute systems with relevance for natural systems, as well as the micro-scale variability and dynamics of chemical reactions on the millisecond time-scale. The design of the BALDER beamline at the MAX IV Laboratory 3 GeV ring has focused on a high flux of photons in a wide energy range, 2.4–40 keV, where the K-edge is covered for the elements S to La, and the L3-edge for all elements heavier than Sb. The overall design of the beamline will allow large flexibility in energy range, beam size and data collection time. The other focus of the beamline design is the possibility to perform multi-technique analyses on samples. Development of sample environment requires focus on implementation of auxiliary methods in such a way that techniques like Fourier transform infrared (FTIR) spectroscopy, UV-Raman spectroscopy, X-ray diffraction and/or mass spectrometry can be performed simultaneously as the XAS study. It will be a flexible system where different instruments can be plugged in and out depending on the needs for the particular investigation. Many research areas will benefit from the properties of the wiggler based light source and the capabilities to perform in-situ and in-operando measurements, for example environmental and geochemical sciences, nuclear chemistry, catalysis, materials sciences, and cultural heritage.

Keywords

X-ray absorption spectroscopy (XAS); beamline design; multi-technique analyses

Published in

Journal of Physics: Conference Series
2016, Volume: 712
Publisher: IOP Publishing

Conference

16th International Conference on X-ray Absorption Fine Structure (XAFS), AUG 23-28, 2015, Karlsruhe, GERMANY

SLU Authors

• Persson, Ingmar

  • The Department of Chemistry and Biotechnology, Swedish University of Agricultural Sciences
    

UKÄ Subject classification

Other Materials Engineering


Publication identifier

DOI: https://doi.org/10.1088/1742-6596/712/1/012023

Permanent link to this page (URI)

https://res.slu.se/id/publ/94342