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Abstract

Complexation between hexavalent neptunium and nitrate was studied in aqueous nitric acid solution using optical absorption, vibrational and X-ray absorption spectroscopies. Distributions of aqueous [NpO2](2+), [NpO2(NO3)](+) and [NpO2(NO3)(2)] species were obtained as a function of nitric acid concentration between 0 and 14 M. The crystal structure of [NpO2(NO3)(2)(H2O)(2)]center dot H2O was determined.

Published in

Dalton Transactions
2013, volume: 42, number: 43, pages: 15275-15279
Publisher: ROYAL SOC CHEMISTRY

SLU Authors

  • Lindqvist-Reis, Patric

    • Karlsruhe Institute of Technology

UKÄ Subject classification

Inorganic Chemistry

Publication identifier

  • DOI: https://doi.org/10.1039/c3dt51650d

Permanent link to this page (URI)

https://res.slu.se/id/publ/95529