Abstract

The time dependent changes of Lu speciation (used as Am(Ill) homologue), initially sorbed onto 2-line ferrihydrite at pH 5.9, during tempering (70 degreesC) to stable crystalline transformation products, goethite and hematite, is studied. Microscopies (AFM, SEM), XRD and FTIR spectroscopy confirm transformation to both goethite and hematite, with a predominance of hematite. XRD investigation of another transformation series at pH 8.0 (75 degreesC, [Lu(III)(initial)] 7 times higher) shows that the cell volume of hematite increases, suggesting the incorporation of Lu in the crystal structure. Extended X-ray absorption fine structure (EXAFS) (pH 5.9 series, 70 degreesC) reveals a shortening of the Lu-0 bond distance and an increase in asymmetry of the first shell with increasing tempering time in the intermediate temper time samples. The intensity of the second peak in the Fourier transform (FT) of the EXAFS increases and splits into two components, The EXAFS data of the end product can be modeled well using a hematite-like cluster, with an isotropic expansion of distances to account for incorporation of Lu into the hematite structure. These results demonstrate that the Lu is incorporated in the crystal lattice of the transformat ion product, as opposed to being occluded or remaining a sorbed species on the surface.

Published in

Environmental Science and Technology
2002, Volume: 36, number: 23, pages: 5092-5099
Publisher: AMER CHEMICAL SOC

UKÄ Subject classification

Inorganic Chemistry


Publication identifier

DOI: https://doi.org/10.1021/es025513f

Permanent link to this page (URI)

https://res.slu.se/id/publ/95561