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Research article2018Peer reviewedOpen access

Peculiarities of Synthesis and Properties of Lignin-Silica Nanocomposites Prepared by Sol-Gel Method

Budnyak, Tetyana M.; Aminzadeh, Selda; Pylypchuk, Ievgen V.; Riazanova, Anastasia V.; Tertykh, Valentin A.; Lindstrom, Mikael E.; Sevastyanova, Olena

Abstract

The development of advanced hybrid materials based on polymers from biorenewable sources and mineral nanoparticles is currently of high importance. In this paper, we applied softwood kraft lignins for the synthesis of lignin/SiO2 nanostructured composites. We described the peculiarities of composites formation in the sol-gel process through the incorporation of the lignin into a silica network during the hydrolysis of tetraethoxysilane (TEOS). The initial activation of lignins was achieved by means of a Mannich reaction with 3-aminopropyltriethoxysilane (APTES). In the study, we present a detailed investigation of the physicochemical characteristics of initial kraft lignins and modified lignins on each step of the synthesis. Thus, 2D-NMR, P-31-NMR, size-exclusion chromatography (SEC) and dynamic light scattering (DLS) were applied to analyze the characteristics of pristine lignins and lignins in dioxan:water solutions. X-Ray photoelectron spectroscopy (XPS) and Fourier transform infrared (FTIR) were used to confirm the formation of the lignin-silica network and characterize the surface and bulk structures of the obtained hybrids. Termogravimetric analysis (TGA) in nitrogen and air atmosphere were applied to a detailed investigation of the thermal properties of pristine lignins and lignins on each step of modification. SEM confirmed the nanostructure of the obtained composites. As was demonstrated, the activation of lignin is crucial for the sol-gel formation of a silica network in order to create novel hybrid materials from lignins and alkoxysilanes (e.g., TEOS). It was concluded that the structure of the lignin had an impact on its reactivity during the activation reaction, and consequently affected the properties of the final hybrid materials.

Keywords

lignin; silica; sol-gel process; hybrid composites; thermal analysis

Published in

Nanomaterials
2018, Volume: 8, number: 11, article number: 950Publisher: MDPI

    UKÄ Subject classification

    Polymer Technologies

    Publication identifier

    DOI: https://doi.org/10.3390/nano8110950

    Permanent link to this page (URI)

    https://res.slu.se/id/publ/97520