Perrhenate ligand as an analog of the methoxide group in alkoxide complexes. Synthesis and X-ray single crystal study of Ta2(OMe)8(ReO4)2

Abstract

The interaction of Ta-2(OMe)(10) with Re2O7 in toluene in 1:2 ratio provided an approach to a new bimetallic complex, Ta-2(OMe)(8)(ReO4)(2)(I), which in its solid state structure and solution behavior displayed a close analogy to the homometallic M-2(OMe)(10), M=Nb, Ta, and to M2O2(OMe)(8), M=MO, W, complexes. (C) 2001 Elsevier Science B.V. All rights reserved.

Keywords

metal alkoxides; methoxide; rhenium complexes; X-ray structure; solution dynamics

Published in

Inorganic Chemistry Communications
2001, Volume: 4, number: 10, pages: 534-536
Publisher: ELSEVIER SCIENCE BV

SLU Authors

• Seisenbaeva, Gulaim

  • Department of Molecular Sciences, Swedish University of Agricultural Sciences
    

• Kessler, Vadim

  • Department of Molecular Sciences, Swedish University of Agricultural Sciences
    

UKÄ Subject classification

Inorganic Chemistry
Materials Chemistry


Publication identifier

DOI: https://doi.org/10.1016/S1387-7003(01)00268-4

Permanent link to this page (URI)

https://res.slu.se/id/publ/50552