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Forskningsartikel2021Vetenskapligt granskad

Interaction between dopamine and the [HPW12O40](2-)Keggin ion-an X-ray and NMR study

Svensson, Fredric G.; Kessler, Vadim G.

Sammanfattning

A novel complex between the [HPW12O40](2-) Keggin ion and the biomolecule dopamine (C8H11NO2), [HPW12O40(dop)(2)] center dot 4H(2)O (1) was crystallized and structurally characterized by single crystal X-ray diffraction and infrared spectrometry. Dopamine interacts via hydrogen bonding between its ammonium group and a W=O oxygen atom in [HPW12O40](2-). NMR analyses (H-1 DOSY) suggests that the [HPW12O40(dop)(2)] complex dissociates in D2O. (C) 2020 Elsevier B.V. All rights reserved.

Nyckelord

Polyoxometalate; Dopamine; Keggin ion; Phosphotungstate

Publicerad i

Journal of Molecular Structure
2021, Volym: 1226, artikelnummer: 129343
Utgivare: ELSEVIER