Sammanfattning

The biologically active Michael acceptor 2-methylene-3-quinuclidinone (MQ) has a unique chemical reactivity and forms several products upon dissolution in water. With the use of X-ray, NMR and LCMS data the structures of two previously incorrectly characterised compounds are rectified. A complex equilibrium in water, containing novel dimeric species of MQ, and its dependence on temperature, pH and concentration is presented.

Publicerad i

Heterocycles
2023, Volym: 106, nummer: 2, sidor: 271-276

SLU författare

• Sandström, Corine

  • Institutionen för molekylära vetenskaper, Sveriges lantbruksuniversitet
    

UKÄ forskningsämne

Organisk kemi


Publikationens identifierare

DOI: https://doi.org/10.3987/COM-22-14797

Permanent länk till denna sida (URI)

https://res.slu.se/id/publ/123432