Sammanfattning

In this study, we synthesised and characterised a new zinc(ii) triazenide for potential use in vapour deposition of zinc sulphide thin films. The compound is volatile and quantitatively sublimes at 80 degrees C under vacuum (0.5 mbar). Thermogravimetric analysis showed a one-step volatilisation with an onset temperature at similar to 125 degrees C and 5% residual mass. The compound also reacted with 2 or 4 molar equivalents of triphenylsilanethiol to give dimeric and monomeric zinc thiolates, respectively. The high volatility, thermal stability, and reactivity with sterically hindered thiols makes this compound a potential candidate for use in vapour deposition of zinc containing thin films.Herein, we synthesise and characterise a new volatile and thermally stable Zn(ii) triazenide. We also react it with a bulky thiol to give two different Zn(ii) thiolates. This new triazenide shows high promise as a precursor for vapour deposition of ZnS thin films.

Publicerad i

Dalton Transactions
2024, Volym: 53, nummer: 13, sidor: 5911-5916
Utgivare: ROYAL SOC CHEMISTRY

SLU författare

• Kessler, Vadim

  • Institutionen för molekylära vetenskaper, Sveriges lantbruksuniversitet
    

UKÄ forskningsämne

Oorganisk kemi


Publikationens identifierare

DOI: https://doi.org/10.1039/d4dt00084f

Permanent länk till denna sida (URI)

https://res.slu.se/id/publ/129207