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Forskningsartikel2008Vetenskapligt granskad

Degradation of polyethylene glycol and hemicellulose in the Vasa

Almkvist, Gunnar; Persson, Ingmar

Sammanfattning

Mass spectrometric analysis of aqueous wood extracts from the Swedish warship Vasa reveals a serious chemical condition in the depth of the wood. The surface is less affected. Polyethylene glycol, used as conservation agent, is affected and partly degraded, and low-molecular fragments from hemicellulose are found at sites with high iron content and low pH. These findings imply a catalytic oxidative process and acidic hydrolysis in the wood, which contributes to a new picture of the challenge of long-term preservation of the Vasa.

Nyckelord

catalytic oxidation; hemicelluloses; hydrolysis; matrix-assisted laser desorption/ionization-time of flight (MALDI-TOF); polyethylene glycol; Vasa; wood degradation

Publicerad i

Holzforschung
2008, Volym: 62, nummer: 1, sidor: 64-70
Utgivare: WALTER DE GRUYTER & CO