Synthesis, crystal, molecular and electronic structure of a novel heterobinuclear alkoxide cluster [(MeO)2ReO(µ-OMe)3MoO(OMe)2]

Kessler, Vadim; Seisenbaeva, Gulaim; Shevelkov, Andrei; Khvorykh, Gennady V.

doi:10.1039/c39950001779

Forskningsartikel1995Vetenskapligt granskad

Synthesis, crystal, molecular and electronic structure of a novel heterobinuclear alkoxide cluster [(MeO)2ReO(µ-OMe)3MoO(OMe)2]

Kessler, Vadim; Seisenbaeva, Gulaim; Shevelkov, Andrei; Khvorykh, Gennady V.

Sammanfattning

The new heterobimetallic methoxide [ReMoO2(OMe)(7)] 1 is obtained in 62% yield by hexane extraction from the electrolyte prepared by anodic oxidation of Re metal in a methanolic solution of [MoO(OMe)(4)] in the presence of LiCl as electrolyte; the molecule of 1 consists of two [MO(OMe)(5)] octahedra with three shared mu-OMe groups; while 1 shows high volatility and under such conditions remains intact, mass spectrometry indicates complete dissociation into homometallic species in the gas phase.

Publicerad i

Journal of the Chemical Society, Chemical Communications
1995, nummer: 17, sidor: 1779-1780
Utgivare: ROYAL SOC CHEMISTRY

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Publikationens identifierare

DOI: https://doi.org/10.1039/c39950001779

Permanent länk till denna sida (URI)

https://res.slu.se/id/publ/50568