Sammanfattning

Herein, we report a new method for the crystal growth of two Zn-based MOFs at room temperature (known MOF-5 and a new modification of [{Zn-2(TBAPy)(H2O)(2)}center dot 3.5DEF](n) (1)) by employing slow diffusion conditions. Employing both Zn-based MOFs with different pore morphology made it possible to discover an anomalous adsorption of L-histidine in 1 of up to 24.3 x 10(15) molecules cm(-2) at 25 degrees C. This is one of the first reports aimed not only at describing a new method for the targeted formation of crystalline MOFs and coordination polymers, but also at demonstrating the use of Zn-based MOFs as potential drug delivery materials, with highly effective adsorption of L-histidine given herein as an example.

Publicerad i

Chemical Communications
2015, Volym: 51, nummer: 100, sidor: 17764-17767
Utgivare: ROYAL SOC CHEMISTRY

SLU författare

• Seisenbaeva, Gulaim

  • Institutionen för kemi och bioteknologi, Sveriges lantbruksuniversitet
    

• Kessler, Vadim

  • Institutionen för molekylära vetenskaper, Sveriges lantbruksuniversitet
    

UKÄ forskningsämne

Biomaterialvetenskap
Materialkemi
Oorganisk kemi


Publikationens identifierare

DOI: https://doi.org/10.1039/c5cc07808c

Permanent länk till denna sida (URI)

https://res.slu.se/id/publ/75427