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Forskningsartikel2006Vetenskapligt granskad

Synthesis of (+)- and (-)-dihydropinidine by diastereoselective dimethylzinc promoted allylation of 2-methyltetrahydropyridine-N-oxide with an allylboronic ester

Eriksson C, Sjodin K, Schlyter F, Hogberg HE

Sammanfattning

The enantiomers of the naturally occurring alkaloid dihydropinidine 1, potential antifeedants against the pine weevil, Hylobius abietis, were prepared by diastereoselective, dimethylzinc mediated addition of pinacolyl 2-propenylboronate 14 to nitrones (R)- and (S)2-methyl tetrahydropyridine-N-oxide 3, prepared from D- and L-alanine, respectively. (c) 2006 Elsevier Ltd. All rights reserved

Publicerad i

Tetrahedron: Asymmetry
2006, Volym: 17, nummer: 7, sidor: 1074-1080
Utgivare: PERGAMON-ELSEVIER SCIENCE LTD

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    Publikationens identifierare

    DOI: https://doi.org/10.1016/j.tetasy.2006.03.033

    Permanent länk till denna sida (URI)

    https://res.slu.se/id/publ/9494