Synthesis and structure of dioxomolybdenum(VI) complex of amine triphenolato ligand

Sammanfattning

Addition of two equivalents of tris(2-hydroxy-3,5-dimethylbenzyl)amine (H(3)Lig) to the solution of MoO2(acac)(2) in MeOH results in the formation of anionic complex, which precipitates as LigH(4)[MoO(2)Lig], a yellow crystalline solid. Crystal structure determinations reveal that the asymmetric unit consists of one [MoO(2)Lig](-) anion, one H(4)Lig(+) cation and two molecules of solvent. Three phenoxide groups of the tetradentate ligand are bonded to cis-MoO22+ -ion in xy-plane, while the amino nitrogen atom completes the distorted octahedral coordination. (C) 2004 Elsevier B.V. All rights reserved.

Nyckelord

molybdenum complex; phenoxide complex; crystal structure; atranes

Publicerad i

Inorganic Chemistry Communications
2004, volym: 7, nummer: 5, sidor: 691-693
Utgivare: ELSEVIER SCIENCE BV

SLU författare

• Kessler, Vadim

  • Institutionen för molekylära vetenskaper, Sveriges lantbruksuniversitet
    

UKÄ forskningsämne

Atom- och molekylfysik och optik

Publikationens identifierare

• DOI: https://doi.org/10.1016/j.inoche.2004.03.020

Permanent länk till denna sida (URI)

https://res.slu.se/id/publ/2909