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The results implicate biogeochemical Si-cycling via formation and dissolution of biogenic silica as processes significantly affecting the dissolved Si transport in boreal systems during April to early October. The Si budget in the river system appeared to be controlled by relative Si enrichment during high discharge events and relative Si depletions in the subarctic mountainous and lake dominated areas. The Si enrichments and depletions were accompanied by decreasing and increasing riverine delta(29)Si and delta(30)Si, respectively. These isotope variations can be explained by release of plant derived silica, depleted in heavier Si isotopes, during the spring snowmelt. Further, increased volumetric contribution from the headwater and losses of dissolved Si due to biogenic silica formation by diatoms in the subarctic lakes at a later period are expected to be responsible for the preferential losses of lighter isotopes, as further verified by land cover analysis. (C) 2010 Elsevier By. All rights reserved.

Nyckelord

Silicon isotopic composition; Dissolved Si; Biogenic silica; Subarctic river system; Biogeochemical Si cycle; MC-ICPMS

Publicerad i

Chemical Geology
2010, volym: 271, nummer: 3-4, sidor: 142-152
Utgivare: ELSEVIER SCIENCE BV

SLU författare

Globala målen (SDG)

SDG14 Hav och marina resurser

UKÄ forskningsämne

Ekologi

Publikationens identifierare

  • DOI: https://doi.org/10.1016/j.chemgeo.2010.01.005

Permanent länk till denna sida (URI)

https://res.slu.se/id/publ/39996