Synthesis and X-ray single crystal study of Co2Al2(O-i Pr)(6)(acac)(4) - first representative of a new structure type for the heterometallic alkoxide complexes

Sammanfattning

The interaction of Co(acac)(2) with Al((OPr)-Pr-i)(3) in 1:1 ratio in toluene on reflux provided with quantitative yield a new heterometallic heteroleptic alkoxide complex, Co2Al2((OPr)-Pr-i)(6)(acac)(4)(I), displaying the so far unprecedented linear chain structure with a M'(mu-OR)(2)M(mu-OR)(2)M(mu-OR)(2)M'core. I appears to be a promising precursor for cobalt oxide-cobalt spinel nanocomposite materials. (C) 2002 Elsevier Science B.V. All rights reserved.

Nyckelord

heterometallic alkoxides; late transition metal alkoxides; alkoxoaluminates; Co spinel; X-ray study

Publicerad i

Inorganic Chemistry Communications
2002, volym: 5, nummer: 11, sidor: 946-948
Utgivare: ELSEVIER SCIENCE BV

SLU författare

• Seisenbaeva, Gulaim

  • Institutionen för molekylära vetenskaper, Sveriges lantbruksuniversitet
    

• Kessler, Vadim

  • Institutionen för molekylära vetenskaper, Sveriges lantbruksuniversitet
    

UKÄ forskningsämne

Oorganisk kemi

Publikationens identifierare

• DOI: https://doi.org/10.1016/S1387-7003(02)00609-3

Permanent länk till denna sida (URI)

https://res.slu.se/id/publ/50548