Kessler, Vadim
- Московский государственный университет имени М. В. Ломоносова
Sammanfattning
The new heterobimetallic methoxide [ReMoO2(OMe)(7)] 1 is obtained in 62% yield by hexane extraction from the electrolyte prepared by anodic oxidation of Re metal in a methanolic solution of [MoO(OMe)(4)] in the presence of LiCl as electrolyte; the molecule of 1 consists of two [MO(OMe)(5)] octahedra with three shared mu-OMe groups; while 1 shows high volatility and under such conditions remains intact, mass spectrometry indicates complete dissociation into homometallic species in the gas phase.
Publicerad i
Journal of the Chemical Society, Chemical Communications
1995, nummer: 17, sidor: 1779-1780
Utgivare: ROYAL SOC CHEMISTRY
SLU författare
Seisenbaeva, Gulaim
- Московская государственная академия тонкой химической технологии имени М. В. Ломоносова (МИТХТ)
UKÄ forskningsämne
Oorganisk kemi
Materialkemi
Publikationens identifierare
- DOI: https://doi.org/10.1039/c39950001779
Permanent länk till denna sida (URI)
https://res.slu.se/id/publ/50568