Synthesis of (+)- and (-)-dihydropinidine by diastereoselective dimethylzinc promoted allylation of 2-methyltetrahydropyridine-N-oxide with an allylboronic ester

Sammanfattning

The enantiomers of the naturally occurring alkaloid dihydropinidine 1, potential antifeedants against the pine weevil, Hylobius abietis, were prepared by diastereoselective, dimethylzinc mediated addition of pinacolyl 2-propenylboronate 14 to nitrones (R)- and (S)2-methyl tetrahydropyridine-N-oxide 3, prepared from D- and L-alanine, respectively. (c) 2006 Elsevier Ltd. All rights reserved

Publicerad i

Tetrahedron: Asymmetry
2006, volym: 17, nummer: 7, sidor: 1074-1080
Utgivare: PERGAMON-ELSEVIER SCIENCE LTD

SLU författare

• Schlyter, Fredrik

  • Institutionen för växtvetenskap, Sveriges lantbruksuniversitet
    

UKÄ forskningsämne

Landskapsarkitektur

Publikationens identifierare

• DOI: https://doi.org/10.1016/j.tetasy.2006.03.033

Permanent länk till denna sida (URI)

https://res.slu.se/id/publ/9494