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Sammanfattning

Iron oxide doped silica films and powders with highly ordered mesostructures of extraordinary temperature stability (up to 1000 degrees C) and iron loading of up to 6 atom% were produced by the use of novel iron alkoxide-coordinated surfactants. Wormhole-like, 2d-centered rectangular, orthorhombic and lamellar mesostructures were obtained by variation of the molar ratios of the metal-surfactant complexes. The influence of a subsequent heat treatment was studied by GI-SAXS, TEM, XRD, and nitrogen sorption techniques. The molecular composition of the films was studied by XPS and EXAFS.

Nyckelord

ORDERED MESOPOROUS SILICAS; RAY-ABSORPTION-SPECTRUM; THIN-FILMS; PHASE-TRANSFORMATION; PRE-EDGE; COMPLEXES; TRANSITION; SCATTERING; OXIDATION; BEHAVIOR

Publicerad i

Journal of Materials Chemistry
2006, volym: 16, nummer: 45, sidor: 4443-4453
Utgivare: ROYAL SOC CHEMISTRY

SLU författare

UKÄ forskningsämne

Oorganisk kemi

Publikationens identifierare

  • DOI: https://doi.org/10.1039/b606386a

Permanent länk till denna sida (URI)

https://res.slu.se/id/publ/9854