Linking the electron donation capacity to the molecular composition of soil dissolved organic matter from the Three Gorges Reservoir areas, China

Sammanfattning

Soil dissolved organic matter (DOM) plays an essential role in the Three Gorges Reservoir (TGR) as a linkage between terrestrial and aquatic systems. In particular, the reducing capacities of soil DOM influence the geochemistry of contaminants such as mercury (Hg). However, few studies have investigated the molecular information of soil DOM and its relationship with relevant geochemical reactivities, including redox properties. We collected samples from eight sites in the TGR areas and studied the link between the molecular characteristics of DOM and their electron donation capacities (EDCs) toward Hg(II). The average kinetic rate and EDC of soil DOM in TGR areas were (0.004 +/- 0.001) hr(-1) and (2.88 +/- 1.39) nmol e(-)/mg DOMbulk, respectively. Results suggest that higher EDCs and relatively rapid kinetics were related to the greater electron donating components of lignin-derived and perhaps pyrogenic DOM, which are the aromatic constituents that influenced the reducing capacities of DOM in the present study. Molecular details revealed that even the typical autochthonous markers are important for the EDCs of DOM as well, in contrast to what is generally assumed. More studies identifying specific DOM molecular components involved in the abiotic reduction of Hg(II) are required to further understand the relations between DOM sources and their redox roles in the environmental fate of contaminants. (C) 2019 The Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences. Published by Elsevier B.V.

Nyckelord

Soil dissolved organic matter; Reducing capacity; Three Gorges Reservoir; Pyrolysis; Natural organic matter; Mercury

Publicerad i

Journal of Environmental Sciences
2020, Volym: 90, sidor: 146-156 Utgivare: SCIENCE PRESS

SLU författare

• Jiang, Tao

  • Institutionen för skogens ekologi och skötsel, Sveriges lantbruksuniversitet
    
  • Southwest University

UKÄ forskningsämne

Miljövetenskap


Publikationens identifierare

DOI: https://doi.org/10.1016/j.jes.2019.11.007

Permanent länk till denna sida (URI)

https://res.slu.se/id/publ/104819