Molecular design approach to a stable heterometallic zirconium-titanium alkoxide - potential precursor of mixed-oxide ceramics

Sammanfattning

New heterometallic interesting trinuclear, Zr{eta(3), mu(2)-NH(c(2)H(4)O(2)}(3)[Ti((OPr)-Pr-i)(3)](2) encountering a nona-coordinated central zirconium atom crystallizes at -30 degreesC from a solution of zirconium and titanium isopropoxides and diethanolamine (Zr:Ti:L = 1:23) in hydrocarbons. Due to its solution stability, this structurally characterized compound is an attractive potential precursor in sol-gel technique for the preparation of mixed metal oxide materials. (C) 2004 Elsevier B.V. All rights reserved.

Nyckelord

heterometallic alkoxides; X-ray structure; nona-coordinated zirconium

Publicerad i

Inorganic Chemistry Communications
2004, volym: 7, nummer: 8, sidor: 953-955
Utgivare: ELSEVIER SCIENCE BV

SLU författare

• Kessler, Vadim

  • Institutionen för molekylära vetenskaper, Sveriges lantbruksuniversitet
    

UKÄ forskningsämne

Oorganisk kemi

Publikationens identifierare

• DOI: https://doi.org/10.1016/j.inoche.2004.06.006

Permanent länk till denna sida (URI)

https://res.slu.se/id/publ/2920