Synthesis and X-ray single crystal study of Co2Al2(O-i Pr)(6)(acac)(4) - first representative of a new structure type for the heterometallic alkoxide complexes

Suslova, Evgeniya V.; Seisenbaeva, Gulaim; Kessler, Vadim

doi:10.1016/S1387-7003(02)00609-3

Research article - Peer-reviewed, 2002

Synthesis and X-ray single crystal study of Co2Al2(O-i Pr)(6)(acac)(4) - first representative of a new structure type for the heterometallic alkoxide complexes

Suslova, Evgeniya V.; Seisenbaeva, Gulaim; Kessler, Vadim

Abstract

The interaction of Co(acac)(2) with Al((OPr)-Pr-i)(3) in 1:1 ratio in toluene on reflux provided with quantitative yield a new heterometallic heteroleptic alkoxide complex, Co2Al2((OPr)-Pr-i)(6)(acac)(4)(I), displaying the so far unprecedented linear chain structure with a M'(mu-OR)(2)M(mu-OR)(2)M(mu-OR)(2)M'core. I appears to be a promising precursor for cobalt oxide-cobalt spinel nanocomposite materials. (C) 2002 Elsevier Science B.V. All rights reserved.

Keywords

heterometallic alkoxides; late transition metal alkoxides; alkoxoaluminates; Co spinel; X-ray study

Published in

Inorganic Chemistry Communications
2002, volume: 5, number: 11, pages: 946-948
Publisher: ELSEVIER SCIENCE BV

Authors' information

Suslova, Evgeniya V.

Lomonosov Moscow State University

Seisenbaeva, Gulaim

Swedish University of Agricultural Sciences, Department of Chemistry

Kessler, Vadim

Swedish University of Agricultural Sciences, Department of Chemistry

UKÄ Subject classification

Inorganic Chemistry

Publication Identifiers

DOI: https://doi.org/10.1016/S1387-7003(02)00609-3

URI (permanent link to this page)

https://res.slu.se/id/publ/50548