Research article - Peer-reviewed, 2002
Synthesis and X-ray single crystal study of Co2Al2(O-i Pr)(6)(acac)(4) - first representative of a new structure type for the heterometallic alkoxide complexes
Suslova, Evgeniya V.; Seisenbaeva, Gulaim; Kessler, VadimAbstract
The interaction of Co(acac)(2) with Al((OPr)-Pr-i)(3) in 1:1 ratio in toluene on reflux provided with quantitative yield a new heterometallic heteroleptic alkoxide complex, Co2Al2((OPr)-Pr-i)(6)(acac)(4)(I), displaying the so far unprecedented linear chain structure with a M'(mu-OR)(2)M(mu-OR)(2)M(mu-OR)(2)M'core. I appears to be a promising precursor for cobalt oxide-cobalt spinel nanocomposite materials. (C) 2002 Elsevier Science B.V. All rights reserved.Keywords
heterometallic alkoxides; late transition metal alkoxides; alkoxoaluminates; Co spinel; X-ray studyPublished in
Inorganic Chemistry Communications2002, volume: 5, number: 11, pages: 946-948
Publisher: ELSEVIER SCIENCE BV
Authors' information
Suslova, Evgeniya V.
Lomonosov Moscow State University
Swedish University of Agricultural Sciences, Department of Chemistry
Swedish University of Agricultural Sciences, Department of Chemistry
UKÄ Subject classification
Inorganic Chemistry
Publication Identifiers
DOI: https://doi.org/10.1016/S1387-7003(02)00609-3
URI (permanent link to this page)
https://res.slu.se/id/publ/50548