Perrhenate ligand as an analog of the methoxide group in alkoxide complexes. Synthesis and X-ray single crystal study of Ta2(OMe)8(ReO4)2

Sammanfattning

The interaction of Ta-2(OMe)(10) with Re2O7 in toluene in 1:2 ratio provided an approach to a new bimetallic complex, Ta-2(OMe)(8)(ReO4)(2)(I), which in its solid state structure and solution behavior displayed a close analogy to the homometallic M-2(OMe)(10), M=Nb, Ta, and to M2O2(OMe)(8), M=MO, W, complexes. (C) 2001 Elsevier Science B.V. All rights reserved.

Nyckelord

metal alkoxides; methoxide; rhenium complexes; X-ray structure; solution dynamics

Publicerad i

Inorganic Chemistry Communications
2001, Volym: 4, nummer: 10, sidor: 534-536 Utgivare: ELSEVIER SCIENCE BV

SLU författare

• Seisenbaeva, Gulaim

  • Institutionen för molekylära vetenskaper, Sveriges lantbruksuniversitet
    

• Kessler, Vadim

  • Institutionen för molekylära vetenskaper, Sveriges lantbruksuniversitet
    

UKÄ forskningsämne

Oorganisk kemi
Materialkemi


Publikationens identifierare

DOI: https://doi.org/10.1016/S1387-7003(01)00268-4

Permanent länk till denna sida (URI)

https://res.slu.se/id/publ/50552