The electrochemical synthesis and X-ray single crystal study of Re4O6(OiPr)10 – a new Rhenium(V, VI) cluster with an unprecedented arrangement of metal–metal bonds

Shcheglov, Pavel A.; Seisenbaeva, Gulaim; Drobot, Dmitrii V.; Kessler, Vadim

doi:10.1016/S1387-7003(01)00154-X

Forskningsartikel2001Vetenskapligt granskad

The electrochemical synthesis and X-ray single crystal study of Re4O6(OiPr)10 – a new Rhenium(V, VI) cluster with an unprecedented arrangement of metal–metal bonds

Shcheglov, Pavel A.; Seisenbaeva, Gulaim; Drobot, Dmitrii V.; Kessler, Vadim

Sammanfattning

The anodic oxidation of rhenium metal in isopropanol at temperatures not exceeding 20 degreesC provides with good yields the crystalline Re4O6(O-i Pr)(10) (I) complex, the molecular structure of which is built up around a practically ideal (Re-Re 2.52-2.54 Angstrom) planar rhombus of metal atoms, being thus connected by five equivalent metal-metal bonds in a system with only six cluster electrons. (C) 2001 Elsevier Science B.V. All rights reserved.

Nyckelord

rhenium alkoxide; electrochemical synthesis; X-ray structure; metal-metal bonds; cluster compounds

Publicerad i

Inorganic Chemistry Communications
2001, Volym: 4, nummer: 5, sidor: 227-229 Utgivare: ELSEVIER SCIENCE BV

SLU författare

Kessler, Vadim
- Institutionen för molekylära vetenskaper, Sveriges lantbruksuniversitet

UKÄ forskningsämne

Oorganisk kemi

Publikationens identifierare

DOI: https://doi.org/10.1016/S1387-7003(01)00154-X

Permanent länk till denna sida (URI)

https://res.slu.se/id/publ/50554