Research article - Peer-reviewed, 1995
Synthesis, crystal, molecular and electronic structure of a novel heterobinuclear alkoxide cluster [(MeO)2ReO(µ-OMe)3MoO(OMe)2]
Kessler, Vadim; Seisenbaeva, Gulaim; Shevelkov, Andrei; Khvorykh, Gennady V.Abstract
The new heterobimetallic methoxide [ReMoO2(OMe)(7)] 1 is obtained in 62% yield by hexane extraction from the electrolyte prepared by anodic oxidation of Re metal in a methanolic solution of [MoO(OMe)(4)] in the presence of LiCl as electrolyte; the molecule of 1 consists of two [MO(OMe)(5)] octahedra with three shared mu-OMe groups; while 1 shows high volatility and under such conditions remains intact, mass spectrometry indicates complete dissociation into homometallic species in the gas phase.Published in
Journal of the Chemical Society, Chemical Communications1995, number: 17, pages: 1779-1780
Publisher: ROYAL SOC CHEMISTRY
Authors' information
Lomonosov Moscow State University
Moscow State Academy of Fine Chemical Technology named after M.V. Lomonosov (MITHT)
Shevelkov, Andrei
Lomonosov Moscow State University
Khvorykh, Gennady V.
Lomonosov Moscow State University
UKÄ Subject classification
Inorganic Chemistry
Materials Chemistry
Publication Identifiers
DOI: https://doi.org/10.1039/c39950001779
URI (permanent link to this page)
https://res.slu.se/id/publ/50568