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Sammanfattning

The concentration profile of 40 polyfluoroalkyl substances (PFAS) in surface water along the River Rhine watershed from the Lake Constance to the North Sea was investigated. The aim of the study was to investigate the influence of point as well as diffuse sources, to estimate fluxes of PFAS into the North Sea and to identify replacement compounds of perfluorooctane sulfonate (PFOS) and perfluorooctanoic acid (PFOA). In addition, an interlaboratory comparison of the method performance was conducted. The PFAS pattern was dominated by perfluorobutane sulfonate (PFBS) and perfluorobutanoic acid (PFBA) with concentrations up to 181 ng/L and 335 ng/L, respectively, which originated from industrial point sources. Fluxes of Sigma PFAS were estimated to be similar to 6 tonnes/year which is much higher than previous estimations. Both, the River Rhine and the River Scheldt, seem to act as important sources of PFAS into the North Sea. (C) 2010 Elsevier Ltd. All rights reserved.

Nyckelord

Polyfluoroalkyl substances (PFAS); Polyfluoroalkyl compounds (PFCs); Perfluorooctane sulfonate (PFOS); Perfluorobutanoic acid (PFBA); Rhine

Publicerad i

Environmental Pollution
2010, volym: 158, nummer: 10, sidor: 3243-3250
Utgivare: ELSEVIER SCI LTD

SLU författare

  • Ahrens, Lutz

    • Helmholtz-Zentrum Geesthacht Zentrum für Material- und Küstenforschung

UKÄ forskningsämne

Organisk kemi
Analytisk kemi
Miljövetenskap

Publikationens identifierare

  • DOI: https://doi.org/10.1016/j.envpol.2010.07.019

Permanent länk till denna sida (URI)

https://res.slu.se/id/publ/53653