The electrochemical synthesis and X-ray single crystal study of Re4O6(OiPr)10 – a new Rhenium(V, VI) cluster with an unprecedented arrangement of metal–metal bonds

Sammanfattning

The anodic oxidation of rhenium metal in isopropanol at temperatures not exceeding 20 degreesC provides with good yields the crystalline Re4O6(O-i Pr)(10) (I) complex, the molecular structure of which is built up around a practically ideal (Re-Re 2.52-2.54 Angstrom) planar rhombus of metal atoms, being thus connected by five equivalent metal-metal bonds in a system with only six cluster electrons. (C) 2001 Elsevier Science B.V. All rights reserved.

Nyckelord

rhenium alkoxide; electrochemical synthesis; X-ray structure; metal-metal bonds; cluster compounds

Publicerad i

Inorganic Chemistry Communications
2001, volym: 4, nummer: 5, sidor: 227-229
Utgivare: ELSEVIER SCIENCE BV

SLU författare

• Seisenbaeva, Gulaim

  • Московская государственная академия тонкой химической технологии имени М. В. Ломоносова (МИТХТ)

• Kessler, Vadim

  • Institutionen för molekylära vetenskaper, Sveriges lantbruksuniversitet
    

UKÄ forskningsämne

Oorganisk kemi

Publikationens identifierare

• DOI: https://doi.org/10.1016/S1387-7003(01)00154-X

Permanent länk till denna sida (URI)

https://res.slu.se/id/publ/50554