Unexpected structural analogy between early and late 3d transition metal alkoxide carboxylates: Synthesis and single crystal X-ray study of Ni-6(OH)(2)(ORN)(6)(OCOR)(2), R-N= C2H4NMe2, R = H, CH3

Sammanfattning

Modification of the liquid Ni(ORN)(2) R-N = C2H4NMe2, with stoichiometric or sub-stoichiometric amounts of carboxylic acids, HCOOH or CH3COOH, results in formation of crystalline heteroleptic complexes Ni-6(OH)(2)(ORN)(6)(OCOR)(2) R = H (1) CH3 (3) with the core structure closely analogous to that observed earlier for hexanuclear titanium (IV) alkoxide carboxylates and derived from hexagonal packing of the donor atoms. (c) 2005 Elsevier Ltd. All rights reserved

Nyckelord

Nickel alkoxides; Molecular precursors; Chemical modi.cation; Acidic reagents; Hybrid magnetic materials

Publicerad i

Polyhedron
2005, volym: 24, nummer: 18, sidor: 3052-3056
Utgivare: PERGAMON-ELSEVIER SCIENCE LTD

SLU författare

• Kessler, Vadim

  • Institutionen för molekylära vetenskaper, Sveriges lantbruksuniversitet
    

UKÄ forskningsämne

Oorganisk kemi

Publikationens identifierare

• DOI: https://doi.org/10.1016/j.poly.2005.06.054

Permanent länk till denna sida (URI)

https://res.slu.se/id/publ/8009